Alicante is a province of eastern Spain, in the southern part of the Valencian Community. It is the second most populated Valencian pro…Alicante is a province of eastern Spain, in the southern part of the Valencian Community. It is the second most populated Valencian province. Likewise, the second and third biggest cities in the Valencian Community—Alicante and Elche, respectively—are located in this province.