Carbon radicals are being used as an intermediate in a variety of synthetic transformations. Because they have just one electron, they tend to be highly reactive, allowing for speedy reactions ...

The two radicals combine via the SH2 reaction to make the new, quaternary group at the end of the alkyl chain. How neatly the reaction worked surprised the team, MacMillan says.

Click reactions—the subject of the 2022 Nobel Prize in Chemistry—come in many forms, but they all share a few key features. Namely, click chemistry forges new chemical bonds quickly ...

Kanazawa University researchers design a radical reaction to build highly functionalized ketones, installing two new carbon-carbon bonds at adjacent positions using a non-metal catalyst Kanazawa ...

In catalytic reactions with organocatalysts, it is difficult to control radical reactions. We designed a thiazolium-type N-heterocyclic carbene catalyst having an N-neopentyl group. This catalyst ...

Kanazawa University. "Vicinal reaction: A radical strategy for linking three organic groups together." ScienceDaily. www.sciencedaily.com / releases / 2019 / 10 / 191031112527.htm (accessed June 2 ...

Carboxylic acids are ubiquitous in bioactive organic molecules and readily available chemical building blocks. Carboxylic ...